Oligonucleotide Synthesis, RNA Raw Materials & Modification

2'-F-Guanosine (iBu) CE Phosphoramidite

Oligonucleotide Synthesis, RNA Raw Materials & Modification

제품 번호CH65028CAS 번호144089-97-4순도99.9% (HPLC)
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제품 개요

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제품군
Oligonucleotide Synthesis, RNA Raw Materials & Modification
분자식
C44H53FN7O8P
분자량
857.9
순도
99.9% (HPLC)

2'-F-Guanosine (iBu) CE Phosphoramidite is the 2'-fluoro guanosine building block for modified-RNA synthesis: 5'-O-(4,4'-dimethoxytrityl)-2'-fluoro-N2-isobutyryl-2'-deoxyguanosine bearing a 3'-O-(2-cyanoethyl N,N-diisopropyl)phosphoramidite group. CH65028 is identified by CAS 144089-97-4, molecular formula C44H53FN7O8P, molecular weight 857.9, PubChem CID 135448972, and InChIKey KJFUMXZZVYMQEU-AOCJBPQJSA-N.

Nucleoside phosphoramidites are the coupling monomers used in automated solid-phase oligonucleotide synthesis: the 3'-phosphoramidite couples to the growing chain, the acid-labile 5'-DMT is removed each cycle, and the N2-isobutyryl base group is removed at final deprotection. The cited oligonucleotide literature discusses 2'-fluoro modifications in relation to RNA affinity and nuclease resistance.

동의어

DMT-2'-F-rG(iBu) phosphoramidite; 5'-O-DMT-2'-fluoro-N2-isobutyryl-2'-deoxyguanosine 3'-CE phosphoramidite

식별 정보 및 규격

Catalog No.CH65028
CAS No.144089-97-4
Molecular FormulaC44H53FN7O8P
Molecular Weight857.9
PubChem CID135448972
InChIKeyKJFUMXZZVYMQEU-AOCJBPQJSA-N
Purity99.9% (HPLC)

보관 조건

-20 C

기술 속성

Monomer class
2'-fluoro RNA CE phosphoramidite
Nucleobase
Guanine
Sugar modification
2'-Fluoro-2'-deoxy
Base protection
N2-Isobutyryl
Packaging
100 mg; 200 mg; 250 mg; 500 mg; 1 g; 5 g; 10 g; 25 g; 100 g; 200 g; 500 g; Custom packaging on request
Water content
<=0.3%
Physical form
white to off-white powder
Stability
stable under recommended storage conditions

응용 맥락

  • 2'-F RNA coupling monomer: the 3'-O-(2-cyanoethyl N,N-diisopropyl)phosphoramidite is the reactive group that couples to the growing oligonucleotide chain in automated solid-phase synthesis.
  • 2'-Fluoro sugar modification: cited oligonucleotide literature discusses 2'-fluoro modifications in relation to RNA affinity and nuclease resistance.
  • 5'-DMT + N2-isobutyryl protection: the acid-labile 5'-DMT is removed each cycle, and the N2-isobutyryl base group is removed at final deprotection.

관련 기술 자료

공개 출처

자주 묻는 질문

What does this 2'-F amidite do in RNA synthesis?

Its 3'-phosphoramidite couples to the growing chain, with 5'-DMT removed each cycle and N2-isobutyryl removed at final deprotection. The product provides a 2'-fluoro guanosine phosphoramidite identity.

How does it relate to 5'-O-DMT-2'-fluoro-N2-isobutyryl-2'-deoxyguanosine?

It is the phosphoramidite of that nucleoside: the 3'-hydroxyl has been converted to a 2-cyanoethyl N,N-diisopropyl phosphoramidite. The precursor is cataloged separately.

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